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INTRODUCTION |
| Many
OEM designers of battery-powered devices are unaware of the impact
that battery cavity and power supply circuitry design has on consumer
satisfaction. An analysis of consumer complaints received by the
Duracell Consumer Relations Center indicates that very few device
failures are due to battery defects. In fact, most problems can
be prevented using simple precautionary measures incorporated into
the design of the device and its battery cavity.
Duracell has worked with leading computer, toy, and power tool
manufacturers to resolve battery cavity and power supply issues.
The benefit to the original equipment manufacturer (OEM) of designing
a consumer friendly battery cavity is increased customer satisfaction,
which ultimately leads to increased sales.
This paper outlines important battery cavity features that should
be designed into any device powered by batteries. |
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Size |
| Frequently,
OEMs design the battery cavity of their device around the battery
of a single manufacturer. Unfortunately, battery dimensions often
vary from manufacturer to manufacturer. For instance, the height
of one manufacturer's 9-volt battery is 1.888 inches, while another's
9-volt battery measures 1.909 inches. While these differences in
size do not appear to be great, the desire by OEM designers to miniaturize
their devices often prevents them from leaving any excess space
in the battery cavity, resulting in a cavity design that will not
accept the batteries of all manufacturers.
Rather than design the battery cavity around the battery of a
single manufacturer whose battery may be a unique size or configuration,
it is recommended that cavity designs be based on IEC (International
Electrotechnical Commission) standards and built to accommodate
maximum and minimum sizes. IEC specifications provide key battery
dimensions, including overall cell height, overall cell diameter,
pip diameter, pip height and diameter of negative cap. Maximum and
minimum values are usually specified, as shown in Figure 1 below.
Figure 1
Along with variations in size, the battery cavity design must also
be able to accommodate unusual battery configurations that fall
within IEC standards. For example, several battery manufacturers
offer batteries with negative recessed terminals that are designed
to prevent contact when they are installed backwards. Unfortunately,
negative recessed terminals will mate only with a contact whose
diameter is less than the battery's positive terminal. Figure 2
illustrates the differences between cells with standard and recessed
terminals.
The IEC drawings should be referenced to determine contact diameter
as well as any other unusual configurations.
Figure 2
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Battery Installation Instructions |
| Some
consumers do not have a full understanding of proper battery care,
usage and installation. Manufacturers can minimize the potential
for users to make common battery installation mistakes, such as
mixing different battery types or inserting them backwards, by including
some type of instructional message on their device.
Duracell recommends that manufacturers inscribe the following information
in the battery cavity behind the cells: the type and size of battery,
the number of cells and their orientation (see Figure 3 below).
Figure 3
Additional instructions should also appear on the battery cavity
door, such as:
- Do not mix alkaline batteries with zinc carbon or rechargeable
batteries.
- Replace all batteries at the same time.
- Remove fully discharged batteries immediately.
By imprinting these messages in the battery cavity and on
the cavity door, the manufacturer can increase the chances of user
readership since the user must open the battery cavity in order
to replace the fully discharged batteries.
Another consideration is the inclination of consumers to insert
batteries with the label side up, as is often the case with non-cylindrical
batteries such as a 9-volt or J battery. To avoid any confusion
by the consumer, it is best to design the cavity so that the battery
is inserted with the label side UP. |
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Battery Contact Materials |
| A variety
of factors must be considered when specifying battery contacts.
Several design principles apply to the substrate. The normal force
provided by the contact must be great enough to hold the battery
in place (even when the device is dropped) and prevent electrical
degradation and resulting instability. Also, contacts must be able
to resist permanent set. This refers to the ability of the contact
to resist permanent deformation with a set number of battery insertions.
Temperature rises, at maximum current drains due to the resistance
of the alloy used, should be minimized. Excessive increases in temperature
will lead to stress relaxation and loss in contact pressure, as
well as to the growth of oxide films, which increase contact resistance.
Coatings are selected to satisfy criterion that the substrate does
not, such as low
conductivity, wear resistance, and corrosion resistance. Gold is
the optimal coating due
to its ability to satisfy all of the above. However, less expensive
alternatives are now
available with similar properties.
Contact failure modes must be avoided, especially with inexpensive
plating materials such as tin. In high humidity and polluted environments,
sulfides can form on base materials and creep through pores in the
coating. The sulfide film, which forms and decreases the conductivity
of the contact, can be prevented with nickel under-plating. Fretting
wear occurs as a result of small amplitude (130pm) oscillatory movement.
The limited motion traps debris such as oxides that result from
the reaction of the base material with the environment. The oxide
debris decreases conductivity and can be prevented by using lubricants
(i. e., polyphenylethers, perfluoroalkylpolyethers, and polyphenylether
microcrystalline wax mixtures).
The following is a list of contact materials recommended for use
with DURACELL
Batteries:
Gold Plating -Provides
the most reliable metal-to-metal contact under all
environmental conditions.
Nickel (Solid) -Provides
excellent resistance to environmental corrosion and is second
only to gold plating as a contact material. Solid nickel can be
drawn or formed.
Nickel Clad Stainless
-Performs almost as well as solid nickel with excellent resistance
to corrosion.
Nickel-Plated Stainless
-A widely used material. Non-plated stainless steel is not
recommended due to the adverse impact of passive films, which develop
on the surface
and result in poor electrical contact.
lnconnel Alloy -Provides
good electrical conductivity and good corrosion resistance.
However, soldering may be difficult unless an active flux is used.
Nickel-Plated Cold-Rolled
Steel - An economical contact material that provides good
contact surface for welding and soldering. A continuous, non-porous
nickel plating of
200 micro-inches is recommended.
A manufacturer of battery contacts should be contacted for
further information on these
and other contact materials. |
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Contact Design |
| The
greatest number of battery complaints received by Duracell is from
users who have inserted the batteries backwards. This error can
result in the charging of batteries, leading to venting and leakage.
Reverse installation of cells can be easily avoided by using a
battery terminal design to prevent contact if batteries are installed
backwards. Two simple solutions are depicted in Figures 4a and 4b.
Figure 4a
Figure 4b
The following is a list of several types of battery terminals which
are available:
Miniature Snap Terminals
- Recommended when the battery will be changed often.
Printed Circuit Board Pins
- Used when the battery is a permanent component.
0.005" Flat Nickel Tab Stock
- Used for a permanent soldered connection.
Single Point Spring or Clip
- For use with miniature cells or a low current drain. Material
must provide a spring pressure of 50 to 80 grams (0.49 to 0.78 N)
on small button cells.
(Caution should be taken to prevent denting cells with excessive
pressure.)
Multiple Point Contact
- Desirable for higher current drains. For larger cylindrical cells,
a pressure of 150 to 175 grams (1.47 to 1.72 N) is recommended.
Contact point is
divided into several individual points or prongs.
Standard Electrical Connector
-Terminals made by a contact manufacturer.
A manufacturer of battery contacts should be contacted for
further information on these
and other types of contacts. |
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Prismatic Battery Contacts |
| Prismatic
batteries like the CP1 (LiMnO2) have for contacts nickel tabs, recessed
around 1mm from the battery top. They are shown as small square
windows on fig. 5, along with the size-matching rechargeable NP-60
(Li-ion) battery. The battery contacts need to have sufficient travel
to penetrate the recess and apply sufficient contact pressure to
minimize contact resistance. Minimum travel of 2.5 mm and minimum
force of 200 grams are used to assure reliable performance in high-drain
devices.

Figure 5
Gold-plated Po-Go contacts meet all of the above requirements.
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Ventilation |
There are three conditions that will cause alkaline batteries to generate
hydrogen gas.
The first, a natural oxidation process, occurs even when the battery
is left idle. Here,
oxidation of the zinc prompts a release of hydrogen from the electrolyte.
These gasses
escape through the crimp and nail hole as well as permeate through
the plastic
grommet. A second process occurs when batteries are discharged below
a safe
cutoff voltage. Electrolysis results when the manganese dioxide is
depleted and excess
zinc and water remain. The gasses could possibly "vent" in this situation.
Venting is the
release of gas pressure through a vent that is designed into the battery
for safety
purposes. Leakage of electrolyte will almost always occur during venting.
The third
process -- charging -- can generate a large volume of gas in a short
period of time. This
happens when a reverse current is forced through the battery or the
battery is inserted
backwards. This situation could also cause the gasses to vent from
the cell.
All three conditions must be accounted for in any device design. Battery
cavity ventilation
should be provided to accommodate low rate gassing from oxidation
and abusive usage
of batteries. Tables 1 and 2 provide an estimate of the amount of
gas generated in each
situation for selected batteries. Actual values will vary due to the
construction of the
battery and the materials used.
Table 1
Table 2
Ventilation may be difficult in certain applications, such as underwater
flashlights, where
the device must be waterproof. In these cases, polypropylene, polyethylene,
or some
other gas permeable material should be considered. The device enclosure
itself could
be made of this material or a membrane of the material of a certain
area can be
designed into the enclosure.
The amount of gas to be released is related to the area and thickness
of the material.
For instance, a 2mm thick polypropylene membrane area of 0.07cm2
is sufficient for
each AA alkaline battery used.
Gassing can be minimized by preventing abusive over-discharge or
charge conditions.
Please contact Duracell for the recommended cutoff voltages for
each battery type.
Reverse installation should also be prevented as mentioned in the
above section on
contact design. Please contact Duracell for further information
and design assistance. |
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Positioning |
| The following guidelines
apply to positioning the battery cavity within the device. First,
the battery cavity should be isolated from the electronic circuitry,
since the metal can in
which the battery chemicals are enclosed is an active part of the
circuitry. If electronic
components come in contact with the battery and pierce the battery
label, failure of the
device may occur.
Second, extra care should be taken to isolate the battery from
heat sinks and exhaust
air flow since heat generated by the electronics will shorten the
service life of the battery.
Lastly, the battery cavity should be designed to contain any leakage
that might occur
under abusive conditions, thus preventing harm to the electronics.
As an option, the
battery cavity could be located at the bottom of the device so any
leaking electrolyte
would fall conveniently away from the circuitry. |
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Accessibility |
| The battery cavity
should be easily accessible to the user, with the exception of those
devices intended for use by children. Since small children often
place objects (such
as batteries) in their mouths, the battery cavity should be designed
to open only with
the aid of a coin or key to prevent access to the batteries by children.
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Configuration |
| A series and/or parallel
connection of batteries within the battery cavity is often desired
to increase voltage and/or capacity. When series and/ or parallel
connections are used,
accidental charging can occur if a battery is inserted back- ward,
even when the device
is turned off. Thus, terminals that prevent the reverse installation
of batteries are
mandatory for series and/or parallel connections. As well, care
should be taken to
illustrate proper insertion of the cells through the use of a drawing
or diagram in the
cavity. Diagrams of series, parallel and series/parallel connections
are shown in
Figures 6a and 6b.
Figure 6a
If terminals to prevent reverse installation are not used, the
number of cells used in
a device should be limited, with consideration given to a worst-case
scenario where
a battery is inserted backward and thus charged. The number of cells
employed
should allow the end-user enough time to turn the device on, determine
that it is
working improperly, and take corrective action. The greater the
number of cells used,
the larger the potential applied across the single reversed cell
and the shorter the
time to venting.
Figure 6b
Four cells are a desirable quantity, given that one fresh cell
charged by three others
takes roughly two minutes to vent. Again, the use of terminals designed
to prevent
the reverse installation of batteries will seriously diminish this
threat and allow for
the use of larger numbers of batteries. |
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Cutoff Voltages |
| Electrolysis occurs
when batteries are deeply discharged. The gas produced in this
reaction will eventually lead to venting. Therefore, the cutoff
voltage should be set
above the level at which this reaction becomes potent. Refer to
the specific battery
data sheet or Duracell technical bulletin to find the recommended
cutoff voltage for
each cell chemistry. Eight-tenths of a volt per cell is the minimum
cutoff voltage for
alkaline cells. Figure 7 illustrates the chemical reactions that
take place during the
discharge of an alkaline cell. Below 0.8V the battery is prone to
gassing.
Figure 7
Other factors need to be considered when setting a cutoff voltage.
For instance, in a
situation where a user mixes old and new batteries, the old battery
can easily reach
deep discharge. To prevent this condition from becoming harmful,
the number of cells
across which the voltage is monitored must be limited. A maximum
of five cells per
monitored string is a safe guideline.
To demonstrate this, Duracell recently tested batteries in a computer
requiring ten AA
alkaline batteries and operating at current drains from 0.5 to 1
amp. The voltage was
monitored over two five-cell strings. One of the ten cells in series
was previously
discharged 90 percent. For test purposes, the voltage across this
one cell was also
monitored. Figure 8 shows the voltage across this cell. Even though
the voltage of
the pre- discharged cell dropped quickly, the 4-volt cutoff for
the five cells (0.8 volt per
cell) enabled the computer to shut down fast enough to prevent venting.
Figure 8
Many devices work in multiple modes, each with different power
requirements, as
shown in Figure 9. For instance, standby and alert modes are found
in pagers. The
cutoff voltage used for these devices must reflect the battery's
voltage in the higher
drain modes. This safeguard prevents the device from shutting down
when the high
drain mode is entered. Therefore, the voltage of the battery in
each of the multiple
modes must be understood throughout the life of the battery. This
allows the designer
to reference cutoff values for high drain modes to load voltages
at lower rate modes.
Device software should be set to prevent the user from switching
to high rate modes
when the battery's voltage falls below critical thresholds. The
device should shut down
once the cutoff voltage for the lowest useful rate mode is attained.
Figure 9
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Charging Protection |
| Charging
of primary batteries should be avoided. Duracell has evaluated several
devices that offer both primary battery and AC power options. In
these devices, mechanical switches are preferred over electrical
versions (i. e., diodes, MOSFETs) due to the absence of leakage
current and forward voltage drop.
Lithium batteries will allow small amounts of leakage current.
For information on the use of diodes with lithium batteries, please
refer to the Duracell Lithium Technical Bulletin, Section 7, or
contact Duracell for technical assistance. |
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SUMMARY |
| Prior to the final
design of any battery-operated device, the battery cavity should
be
tested under worst case conditions. Typical scenarios include repeated
usage and
exposure to high heat and humidity. Key battery cavity parameters
should be checked,
such as corrosion on battery terminals and the ability of the cavity
to vent gasses
emitted by the battery. Tests should be performed which take into
consideration the
above variables to ensure optimum battery-to-device fit and performance.
Original equipment manufacturers are advised to work closely with
a major battery
manufacturer capable of providing technical assistance on both the
battery and its
usage. Duracell encourages OEMs to consult their nearest Duracell
sales office for
further information. |
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CAUTION |
This guide is intended
for general information only and the material contained herein
may be inapplicable or incomplete if applied to certain specific battery
applications. All
device designs should be fully tested to take into consideration any
battery operating
variables and to insure optimum battery-to-device fit, performance
and safety. Duracell
assumes no responsibility for specific device designs as related to
battery usage or
otherwise.
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